The team’s line up will also include No. 16 Sloan Stephens and No. 27 Varvara Lepchenko.
The winner of the match will advance to the 2014 world group and have a chance to grab the Fed Cup title next year. The non-winning team will be moved to world group II in 2014.
The US team will face No. 54 Sofia Arvidsson, No. 65 Johanna Larsson, No. 425 Hilda Melander and No. 489 Sandra Roma of Sweden.
Currently, Serena is ranked No.1 in the world while Venus is ranked No. 22.
Do you think the Williams sisters will help the US advance to the next round? Find out more about this news in this report from Associated Press.